WebAug 24, 2007 · Abstract The synergistic extraction with N,N,N′,N′‐tetrakis(2‐methylpyridyl)‐ethylenediamine (TPEN) and di(2‐ethylhexyl)phosphoric acid (D2EHPA) in 1‐octanol demonstrates good selectivity for Am(III) over Ln(III) in solutions containing macroscopic concentrations of the latter. The maximum apparent separation … WebA new synthetic chelating N–hydroxy–N–trioctyl iminophosphorane (HTIP) was prepared through the reaction of trioctylphosphine oxide (TOPO) with N–hydroxylamine hydrochloride in the presence of a Lewis acid (AlCl3). Specifications for the HTIP chelating ligand were successfully determined using many analytical techniques, 13C–NMR, …
Solvent Extraction and Ion Exchange - Taylor & Francis
WebJan 1, 2024 · In D2EHPA, the oxygen atoms of P O form coordinate covalent bonds with europium and samarium ions to form metal complexes. From Fig. 3 it is observed that the plot between log D Vs log extractant gives linear slope with a value around 3.0, which explained during extraction process participation of 3 mol of D2EHPA per one mole of … WebThis paper presents the results of applying hydrophobic deep eutectic solvents (HDESs) for the extraction of metal ions from a real hydrochloric acid solution after leaching the cathodes of three different types of Li-ion batteries. Aliquat 336-, D2EHPA- and menthol-based HDESs developed by us were used in this study. The optimal HCl leaching conditions … real atheology twitter
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WebAround 96.6% of Mn(II) was extracted using two extraction stages at O/A ratio of 1:1 and pHe (equilibrium pH) of 4. Furthermore, FTIR method showed that TBP and D2EHPA were bonding via a hydrogen bond. In addition, by slope analysis method the stoichiometric coefficient of Mn was found to be 4 for D2EHPA and 1 for TBP. Show less WebUsing a structure estimation method based on molecular connectivity indices (1), the Koc of bis (2-ethylhexyl) phosphate can be estimated to be 1.7X10+4 (SRC). According to a classification scheme (2), this estimated Koc value suggests that bis (2-ethylhexyl) phosphate is expected to be immobile in soil. The estimated pKa of bis (2-ethylhexyl ... WebOct 1, 2024 · A novel process of recovery of Mn as lithium ion-sieve from H 2 SO 4 leaching liquor of spent lithium-ion batteries was developed. After precipitation of Fe 3+ and Cu 2+ in the leaching liquor, Mn was recovered with D2EHPA extraction followed by two-step stripping with H 2 SO 4 solution. Lithium ion-sieve was synthesized by oxidation of the … real athletic bilbao en direct